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电位滴定同时测定磷酸与亚磷酸的两种数据处理方法比较
引用本文:董慧茹,董本东,王萍,张传宇.电位滴定同时测定磷酸与亚磷酸的两种数据处理方法比较[J].石油化工高等学校学报,1994,7(4):13-17.
作者姓名:董慧茹  董本东  王萍  张传宇
作者单位:辽阳石油化工高等专科学校
摘    要:分别利用CPV矩阵和主成分分析两种方法来处理多组分分析中的电位滴定数据,同时测定了亚磷酸原料中磷酸与亚磷酸含量.实验结果表明,主成分分析法的准确度和精密度均优于CPV矩阵法.

关 键 词:电位滴定,同时测定,主成分分析,磷酸,亚磷酸/CPV矩阵法

Comparision of Two Methods Processing Data in the Potentiometric Titrating Simultaneous Determination of Phosphoric Acid and Phosphorous Acid
Dong Huiru, Dong Bendong, Wang Ping, Zhang Chuanyu.Comparision of Two Methods Processing Data in the Potentiometric Titrating Simultaneous Determination of Phosphoric Acid and Phosphorous Acid[J].Journal of Petrochemical Universities,1994,7(4):13-17.
Authors:Dong Huiru  Dong Bendong  Wang Ping  Zhang Chuanyu
Abstract:In this paper, the potentiometric titrating data in multicomponent analysis were processed respectively by CPV matrix method and principal component analysis (PCA).The components of phosphoric acid and phosphorous acid in phosphorous materials were determined simultaneously. The experimental results show that the accuracy of PCA is better that CPV matrix method.
Keywords:Potentiometric titrating  Simultaneous determination  Principal component analysis  Phosphoric acid  Phosphorous acid/CPV matrix method
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