| 电弧法制备洋葱状富勒烯的工艺研究 |
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| 引用本文： | 章海霞,王晓敏,王海英,刘旭光,许并社.电弧法制备洋葱状富勒烯的工艺研究[J].新型炭材料,2004,19(1):61-64. |
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| 作者姓名： | 章海霞 王晓敏 王海英 刘旭光 许并社 |
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| 作者单位： | 太原理工大学,材料科学与工程学院,山西,太原,030024 |
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| 基金项目： | 国家自然科学基金(90306014,20271037)，国家杰出青年科学基金(50025103)，中日国际合作项目(50311140138)，山西省自然科学基金(20031021,20031049) ~~ |
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| 摘 要： | 运用纳米Bi2O3微粒作催化剂，在电弧放电条件下，进行了纳米洋葱状富勒烯大量合成的研究。并用透射电镜对产物的形貌、结构进行了观察与分析。结果表明：纳米洋葱状富勒烯的石墨化程度很高，且直径均匀(约为25nm)，结构较完善；同时伴有单核纳米洋葱状富勒烯向多核纳米洋葱状富勒烯的转变。为洋葱状富勒烯的宏量制备提供了有利线索。
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| 关 键 词： | 电弧法 电弧放电 纳米洋葱状富勒烯 催化剂 纳米Bi2O3微粒 透射电镜 碳化学 |
| 文章编号： | 1007-8827(2004)01-0061-04 |
| 修稿时间： | 2003年10月15 |
The preparation of nano-onion-like fullerencs by arc discharge |
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| ZHANG Hai-xia,WANG Xiao-min,WANG Hai-ying,LIU Xu-guang,XU Bing-she.The preparation of nano-onion-like fullerencs by arc discharge[J].New Carbon Materials,2004,19(1):61-64. |
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| Authors: | ZHANG Hai-xia WANG Xiao-min WANG Hai-ying LIU Xu-guang XU Bing-she |
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| Abstract: | The synthesis of nano-onion-like fullerenes on a large scale by the arc discharge method was investigated using Bi_2O_3 as catalyst. Transmission electron microscopy was used to characterize the morphologies and microstructures of the product. Results indicated that the nano-onion-like fullerenes were perfectly structured and highly graphitized, with uniform external diameter of about 25nm. Two kinds of nano-onion-like fullerenes were obtained: 1) Single-nuclei onion-like fullerenes; 2) Multiple-nuclei onion-like fullerenes. The investigation pointed to a possible routine for large scale synthesis of onion-like fullerenes. |
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| Keywords: | Catalyst Arc discharge Nano-onion-like fullerenes |
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