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Density effects in internal-energy transport in polyatomic gases
Authors:L. Monchick
Affiliation:(1) 2801 Greenvale Street, 20815-3122 Chevy Chase, Maryland, USA
Abstract:The revised Enskog theory is used in a heuristic way to modify the Wang Chang-Uhlenbeck quantum kinetic equation for polyatomic gases close to thermodynamic equilibrium. The density effects predicted for the total and internal thermal conductivities are in qualitative agreement with recent molecular dynamic calculations, suggesting that inelastic effects should be included in dense fluid transport theory. Paper dedicated to Professor Edward A. Mason.
Keywords:density  internal energy  polyatomic gases  revised Enskog theory  rotational relaxation  thermal conductivity  transport properties  Wang Chang-Uhlenbeck equation
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