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AB_3型La-Mg-Ni系稀土贮氢合金电极合金结构和贮氢性能
引用本文:吴静然. AB_3型La-Mg-Ni系稀土贮氢合金电极合金结构和贮氢性能[J]. 热加工工艺, 2010, 39(2)
作者姓名:吴静然
作者单位:承德石油高等专科学校,机械工程系,河北,承德,067000
摘    要:用感应熔炼的方法制备了AB_3型La-Mg-Ni系稀土贮氰电极合金,采用X射线衍射、Sievert型测试仪、三电极测试体系研究了合金的相结构、吸氢性能、电化学性能.X射线衍射分析结果表明,AB_3型La-Mg-Ni系稀土贮氢电极合金均南(La,Mg)Ni,相、(La,Mg)_2Ni_7相及少量杂质相组成,为多相结构;贮氢性能实验研究表明,具有PuNi_3结构的LaNi_3,型合金的吸氧量高于具有CaCu_5结构的LaNi_5型合金.

关 键 词:贮氧电极合金  相结构  贮氢性能

Phase Structure and Hydrogen Storage Properties of La-Mg-Ni System AB_3 Hydrogen Storage Electrode Alloys
WU Jingran. Phase Structure and Hydrogen Storage Properties of La-Mg-Ni System AB_3 Hydrogen Storage Electrode Alloys[J]. Hot Working Technology, 2010, 39(2)
Authors:WU Jingran
Abstract:The La-Mg-Ni system AB_3 hydrogen storage electrode alloys were prepared by induction melting under Ar gas atmosphere.The phase structure and electro chemical properties of these alloys were investigated by means of XRD.Sievert instrument and tri-electrode test system.XRD analyses show that these alloys consist of(La,Mg)Ni_3 phase,(La,Mg)_2Ni_7 phase and a little impurity.The results show that maximum storage capacity of the alloys with PuNi_3 structure is much higher than that of LaNi_5 alloys with CaCu_5 structure.
Keywords:hydrogen storage alloys  phase structure  hydrogen storage properties
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