| 丙烯腈与衣康酸在1-丁基-3-甲基咪唑氯化物中的共聚反应 |
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| 引用本文： | 张青,杨春雷,余优霞,薛明,张玉梅,王华平.丙烯腈与衣康酸在1-丁基-3-甲基咪唑氯化物中的共聚反应[J].合成技术及应用,2011,26(2):1-6,24. |
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| 作者姓名： | 张青 杨春雷 余优霞 薛明 张玉梅 王华平 |
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| 作者单位： | 东华大学材料科学与工程学院纤维材料改性国家重点实验室,上海,201620 |
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| 基金项目： | 上海市教委科研创新项目(02244); 曙光计划跟踪项目(08GG11)的资助 |
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| 摘 要： | 以离子液体1-丁基-3-甲基咪唑氯化物为溶剂,研究了丙烯腈（AN）与衣康酸（IA）的二元共聚反应。利用红外光谱和元素分析法对聚合物进行了化学结构和组成分析,结果表明在离子液体中制备的AN与IA的共聚物与在常规溶剂中的产物有相同的结构并且组成相近。对共聚反应动力学进行了详细探讨,确定了AN与IA在离子液体中较适宜的反应条...
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| 关 键 词： | 丙烯腈 衣康酸 离子液体 自由基聚合 热性能 |
Radical copolymerization of acrylonitrile and Itaconic acid using 1-buty-3-methylimidazolium chloride as solvent |
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| Zhang Qing,Yang Chunlei,Yu Youxia,Xue Ming,Zhang Yumei,Wang Huaping.Radical copolymerization of acrylonitrile and Itaconic acid using 1-buty-3-methylimidazolium chloride as solvent[J].Synthetic Technology and Application,2011,26(2):1-6,24. |
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| Authors: | Zhang Qing Yang Chunlei Yu Youxia Xue Ming Zhang Yumei Wang Huaping |
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| Affiliation: | Zhang Qing,Yang Chunlei,Yu Youxia,Xue Ming,Zhang Yumei,Wang Huaping (Donghua University,State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,Shanghai 201620,China) |
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| Abstract: | The free radical copolymerization of acrylonitrile(AN) and itaconic acid(IA) in l-buty-3-methy-limidazolium chloride(bmim]Cl) were investigated.The chemical structure and composition of the copolymers were analyzed by Fourier Transform Infrared Spectroscopy(FT-IR) and elemental analysis.It was shown that the obtained polymers possessed the same structure and composition with that prepared in conventional solvents.The polymerization kinetics was discussed in detail.It was concluded that the proper copolymer... |
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| Keywords: | acrylonitrile itaconic acid ionic liquid free radical polymerization thermal property |
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