Organically templated Np(IV) coordination polymer with in situ formed oxalate anion (ImidazoleH)[Np(C2O4)(CH3SO3)3(H2O)2] |
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| Authors: | Grigory B Andreev Nina A Budantseva Ivan G Tananaev Boris F Myasoedov |
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| Affiliation: | aA.N. Frumkin Institute of Physical Chemistry and Electrochemistry of Russian Academy of Sciences, 31 Leninskiy pr., Moscow 119991, Russia |
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| Abstract: | The reaction of Np(V) methanesulfonate solution with imidazole led to the in situ formation of oxalic acid and the reduction of Np(V) to Np(IV). As a result, the novel organically templated organic polymer, (ImidazoleH)Np(C2O4)(CH3SO3)3(H2O)2], was formed. The structure consists of infinite chains of Np(C2O4)(CH3SO3)3(H2O)2]− and imidazolium cations. The crystal structure is confirmed by IR and UV–vis spectroscopic data. This complex is the first example of structurally characterized 1:1 An(IV) oxalate. |
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| Keywords: | Neptunium Coordination polymer Crystal structure Electronic spectrum IR spectrum In situ synthesis |
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