Estimated NH3-volatilization losses from surface-applied urea on a wet calcareous Vertisol

Severe losses of NH₃ by volatilization are often reported when urea is surface applied to calcareous soils. Applications on wet soils may increase these losses. This study with N rates of 0, 20, 40, 80, 160, and 320 kg ha^?1 estimates the efficiency of urea application and predicts NH₃-volatilization losses when urea is surface applied on a wet calcareous soil. Placements consisted of three different methods of applying urea on or in the dry soil just prior to irrigation and a surface-broadcast treatment following irrigation. There were no significant yield differences between dry-soil placements, but all dry-soil placements gave significantly higher yields than did broadcast placement of urea on the wet soil. Thus, a second-order regression equation relating N rate and yield for dry-soil placements and another for wet-soil placement were used to determine the efficiency of wet- vs dry-soil applications of urea and to predict NH₃-volatilization losses from the wet soil. The efficiency was determined by three different procedures. The first compared the amount of N needed for wet- vs dry-soil conditions to produce discrete yields. The second compared the slope of the yield curves at discrete yield levels to determine the ratio of the amount of N needed to produce one additional increment of yield under wet- vs dry-soil conditions. The third was an estimation of the availability coefficient according to a method recently developed by HR Tejeda and others. Predicted NH₃ -volatilization losses were calculated from the efficiency values because loss of NH₃ from urea applied on or in dry soil followed very shortly by an irrigation should be almost nil. The efficiency factors averaged 55% for the first procedure and 51% for the second while the availability coefficient was 59%. Thus, the average estimate for efficiency of urea on wet vs dry soil was 55% and predicted losses of N by NH₃ volatilization averaged 45% when urea was applied to the wet surface of this calcareous soil.