| 磺化聚醚醚酮磺化度的测定及其对质子交换膜性能的影响 |
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| 引用本文： | 董云凤,谭孝林,郭强,李夏,李丹,李萌. 磺化聚醚醚酮磺化度的测定及其对质子交换膜性能的影响[J]. 理化检验(物理分册), 2011, 0(9): 535-538 |
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| 作者姓名： | 董云凤 谭孝林 郭强 李夏 李丹 李萌 |
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| 作者单位： | 上海大学材料科学与工程学院; |
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| 基金项目： | 国家自然科学基金项目(50975167); 上海市重点学科项目(S30107); 国家级大学生创新基金项目(CXJJ09-17) |
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| 摘 要： | 以聚醚醚酮（PEEK）和浓硫酸为原料，采用后磺化法制备不同磺化度的磺化聚醚醚酮（SPEEK）。采用核磁共振法测定SPEEK的磺化度，并研究了磺化度对SPEEK质子交换膜性能的影响。结果表明：磺化度高于80％的SPEEK会发生过度溶胀，而磺化度为48％～65％范围的SPEEK膜表现出较好的质子传导率、阻醇性能及抗吸水性能。
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| 关 键 词： | 磺化聚醚醚铜 磺化度 核磁共振谱 质子交换膜 |
Testing of Sulfonation Degree of SPEEK and its Effect on Properties of Proton Exchange Membrane |
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| DONG Yun-feng,TAN Xiao-lin,GUO Qiang,LI Xia,LI Dan,LI Meng. Testing of Sulfonation Degree of SPEEK and its Effect on Properties of Proton Exchange Membrane[J]. Physical Testing and Chemical Analysis Part A:Physical Testing, 2011, 0(9): 535-538 |
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| Authors: | DONG Yun-feng TAN Xiao-lin GUO Qiang LI Xia LI Dan LI Meng |
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| Affiliation: | DONG Yun-feng,TAN Xiao-lin,GUO Qiang,LI Xia,LI Dan,LI Meng (School of Materials Science and Engineering.Shanghai University,Shanghai 201800,China) |
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| Abstract: | Sulfonated polyether ether ketone （SPEEK） with various degree of sulfonation （DS） was prepared by commercial Victrex PEEK and concentrated sulphuric acid. Nuclear magnetic resonance （NMR） was used to measure the DS of SPEEK, then the influence of the DS to SPEEK performance was studied. Results showed that when the DS was above 80%, SPEEK would be excessive swelling, while the DS was between 48%-65%, SPEEK has good proton conductivity and methanol resistance properties and water absorption. |
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| Keywords: | SPEEK degree of sulfonation nuclear magnetic resonance spectrum proton exchange membrane |
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