Microwave dielectric properties of mixed phase ceramics, Ba(Zn1/3Ta2/3)O3–xCaTiO3 and xMgTiO3–yCaTiO3–z(Nd2O3,wTiO2)

The effect of different chemical compositions on the microwave dielectric properties of Ba(Zn_1/3Ta_2/3)O₃–xCaTiO₃ and xMgTiO₃–yCaTiO₃–z(Nd₂O₃,wTiO₂) was studied. High fQ dielectrics were designed by optimizing composition and firing conditions. Adding up to 1 mol % CaTiO₃ to Ba(Zn_1/3Ta_2/3)O₃ increased ε_r from 25 to 30 at a firing temperature of 1450 °C, and produced very high fQ values of more than 100 000 GHz at a firing temperature of 1550 °C. EPMA and XRD suggested that ceramics based on Ba(Zn_1/3Ta_2/3)O₃ with CaTiO₃ had mixed phases of Ba(Zn_1/3Ta_2/3)O₃ and Ca–Ti–Zn–O. Addition of CaTiO₃ increased the Ba(Zn_1/3Ta_2/3)O₃ peak observed in XRD and decreased the Ba₃Ta₂O₈ peak. Prolonged sintering of Ba(Zn_1/3Ta_2/3)O₃ with CaTiO₃ increased the fQ value but kept ε_r constant. 0.5MgTiO₃–0.5CaTiO₃–z(Nd₂O₃,wTiO₂) showed a high dielectric constant ε_r>40 and fQ>20 000 GHz. When w=1, τ_f decreased linearly with z around 0 ppm/ °C in 0.5MgTiO₃–0.5CaTiO₃–z(Nd₂O₃,TiO₂) (0.25≤z≤0.5). X-ray and EDX analysis revealed a mixed phase matrix of MgTiO₃ and (Ca_1?αNd_2α/3)Ti_βO₃. It was concluded that ε_r of the high fQ materials Ba(Zn_1/3Ta_2/3)O₃–xCaTiO₃ and xMgTiO₃–yCaTiO₃–z(Nd₂O₃,wTiO₂) would be increased by varying their chemical compositions, x, y, z, and w, and that their fQ value would be improved by appropriate choices of heating temperature and time.