| 纳米铁/碳纳米管复合氧阴极电-Fenton降解RhB |
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| 引用本文： | 梅涛,刘娟,李金坡,张礼知,艾智慧.纳米铁/碳纳米管复合氧阴极电-Fenton降解RhB[J].化工进展,2007,26(8):1166-1169. |
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| 作者姓名： | 梅涛 刘娟 李金坡 张礼知 艾智慧 |
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| 作者单位： | 华中师范大学化学学院,湖北,武汉,430079 |
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| 基金项目： | 国家自然科学基金资助项目(No.20503009,20673041)。 |
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| 摘 要： | 制备了纳米铁/碳纳米管(Fe/CNTs)复合氧阴电极,通过SEM、EDS、XRD对电极进行了表征。基于该氧阴电极中性条件下电-Fenton降解Rhodamin B(RhB)溶液的试验表明,外加电压1.2 V、通入空气量0.1 m3/h、反应120 min、5mg/L的RhB溶液降解率达到92.1%,说明H2O2和离子态铁可以通过电化学还原在该氧阴极表面高效产生,RhB可通过E-Fenton反应高效去除。
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| 关 键 词： | 碳纳米管 纳米铁 电-Fenton反应 罗丹明(RhB) |
| 文章编号： | 1000-6613（2007）08-1166-04 |
| 收稿时间： | 2007-01-31 |
| 修稿时间： | 2007-01-312007-03-08 |
Degradation of RhB by electro-Fenton reaction using a nanoscale Fe/CNTs composites cathode |
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| MEI Tao,LIU Juan,LI Jinpo,ZHANG Lizhi,AI Zhihui.Degradation of RhB by electro-Fenton reaction using a nanoscale Fe/CNTs composites cathode[J].Chemical Industry and Engineering Progress,2007,26(8):1166-1169. |
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| Authors: | MEI Tao LIU Juan LI Jinpo ZHANG Lizhi AI Zhihui |
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| Affiliation: | School of Chemistry, Central China Normal University, Wuhan 430079, Hubei, China |
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| Abstract: | In this study,a nanoscale iron/carbon nanotube(CNT) composite cathode was synthesized and evaluated by X-ray diffraction(XRD),scanning electron microscopy(SEM),and engery dispersive X-ray spectroscopy(EDX) respectively.It was found that 92.1% degradation of 5 mg/L Rhodamin B(RhB) was achieved in the presence of 1.2V potential and air(0.1m3/h) based on the eletro-Fenton reaction using a nanoscale Fe/CNTs composite cathode at a neutral pH.The results indicated that both H2O2 and iron ions could be effectively generated by electrochemical reduction from Fe/CNTs cathode and RhB could be rapidly eliminated. |
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| Keywords: | carbon nanotube nanoscale iron electro-Fenton reaction RhB |
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