Abstract: | Unambiguous evidence has been provided for the existence of a branched structure in liquid epoxide resins which have been subjected to postepoxidation with excess epichlorohydrin in the presence of a powerful nucleophilic catalyst, tetramethylammonium chloride. Gel chromatography of the resin on Sephadex LH-20 followed by isolation and identification of the relevant fraction by spectroscopic techniques revealed the presence of a novel trifunctional epoxide having a molecular weight of 680. |