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Thermal decomposition of polyurethane pressure-sensitive adhesives dispersions
Authors:Zbigniew Czech  Robert Pełech
Affiliation:Institute of Chemical Organic Technology, West Pomeranian University of Technology, Szczecin, Pulaskiego 10, 70-322 Szczecin, Poland
Abstract:The thermal degradation of polyurethane pressure-sensitive adhesives (PSAs) at temperature 600 °C was investigated by the application of pyrolysis-gas chromatography technique. The present study was undertaken in order to determine the key thermal degradation products of polyurethane PSA based on isophorone diisocyanate (IPDI), polypropylene glycol (PPG), hydroxylated polybutadiene (HTPB), dimethylolpropionic acid (DMPA) and to elucidate the mechanism of the polyurethane PSAs pyrolysis.
Keywords:Polyurethane   Pressure-sensitive adhesives   Thermal degradation   Pyrolysis   Breakdown products
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