| 含短氟碳侧链及芳香环的甲基丙烯酰类单体的合成与表征 |
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| 引用本文： | 冯泽峰,谭业邦,邢卫国,袁培林,王明刚.含短氟碳侧链及芳香环的甲基丙烯酰类单体的合成与表征[J].化学试剂,2012,34(2):113-116. |
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| 作者姓名： | 冯泽峰 谭业邦 邢卫国 袁培林 王明刚 |
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| 作者单位： | 1. 山东大学化学与化工学院特种功能聚集体材料教育部重点实验室,山东济南,250100
2. 济南化工产业园区管委会,山东济南,250119 |
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| 基金项目： | 济南高校自主创新计划资助项目 |
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| 摘 要： | 以全氟己基碘烷为原料通过一锅法制备了3-(全氟正己基)环氧丙烷,总收率达79.6%。从该环氧丙烷出发合成分离出了5种含短氟碳侧链及芳香环侧基的甲基丙烯酰类单体,并探讨了中间体含氟醇的最佳合成条件;通过1HNMR、13CNMR、19FNMR对合成单体进行了表征。
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| 关 键 词： | 醋酸烯丙酯 开环反应 全氟己基环氧丙烷 含氟甲基丙烯酸酯 |
Synthesis and characterization of methacryloyl monomers containing short perfluorocarbon side chains and aromatic rings |
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| FENG Ze-feng
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TAN Ye-bang
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XING Wei-guo
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YUAN Pei-lin
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WANG Ming-gang.Synthesis and characterization of methacryloyl monomers containing short perfluorocarbon side chains and aromatic rings[J].Chemical Reagents,2012,34(2):113-116. |
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| Authors: | FENG Ze-feng TAN Ye-bang XING Wei-guo YUAN Pei-lin WANG Ming-gang |
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| Affiliation: | 1(1.Key Laboratory of Special Functional Aggregated Materials,Ministry of Education;College of Chemistry and Chemical Engineering,Shandong University,Jinan 250100,China;2.Administrative Committee of Jinan Chemical Industrial Zone,Jinan 250119,China) |
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| Abstract: | Perfluorohexyl iodide has been used as a raw material in preparing 3-perfluorohexyl-1,2-epoxypropane(PFOP) by one-pot reaction.The total yield reached 79.6%.Starting from 3-perfluorohexyl-1,2-epoxypropane,five novel methacryloyl monomers containing aromatic rings and short perfluorocarbon side chains were obtained;and the optimal conditions of the intermediates were discussed.The monomers were confirmed by 1HNMR,13CNMR and 19FNMR. |
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| Keywords: | allyl acetate ring opening perfluorohexyl epoxypropane fluorinated methacrylate ester |
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