| 一步法松香改性十二烷基酚醛树脂的合成 |
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| 引用本文： | 黄宝铨. 一步法松香改性十二烷基酚醛树脂的合成[J]. 精细石油化工进展, 2006, 7(1): 30-33 |
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| 作者姓名： | 黄宝铨 |
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| 作者单位： | 福建师范大学化学与材料学院,福州,350007 |
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| 摘 要： | 在氧化镁催化剂存在下。用一步法工艺由松香、十二烷基酚、反丁烯二酸、固体甲醛等合成松香改性十二烷基酚醛树脂，确定了松香改性十二烷基酚醛树脂的最佳组成：松香、反丁烯二酸、酚醛、季戊四醇用量分别为50％～55％，1．5％，2％，35％-40％，10％-15％，酚醛摩尔比为1：2。考察了反丁烯二酸用量、烷基酚结构、甲醛种类对产品性能的影响。
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| 关 键 词： | 松香 改性 十二烷基酚醛树脂 一步法合成 |
| 收稿时间： | 2005-10-10 |
| 修稿时间： | 2005-10-10 |
One-Step Synthesis of Rosin Modified Dodecylphenolic Resin |
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| Huang Baoquan. One-Step Synthesis of Rosin Modified Dodecylphenolic Resin[J]. Advances in Fine Petrochemicals, 2006, 7(1): 30-33 |
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| Authors: | Huang Baoquan |
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| Abstract: | Rosin modified dodecylphenolic resin was synthesized from rosin, fumaric acid, dodecylphenol and formaldehyde,etc.as raw material in the presence of magnesium oxide by one - step method.The optimum composition of rosin modified dodecylphenolic resin was determined as follows: the contents of rosin, fumaric acid, phenolic aldehyde,pentaerythritol were 50% - 55% ,1.5% - 2% ,35% - 40% ,10% - 15% respectively and molar ratio of dodecylphenolic to formaldehyde was 1:2. The effects of fumaric acid amount, alkylphenol structure and formaldehyde kinds on the properties such as viscosity, solubility and softening point were examined. |
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| Keywords: | rosin modification dodecylphenolic resin one - step synthesis |
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