Effect of retained austenite on the hydrogen content and effective diffusivity of martensitic structure |
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Authors: | S L I Chan H L Lee J R Yang |
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Affiliation: | (1) The Graduate Institute of Materials Science and Engineering, National Taiwan University, Taipei;(2) The Graduate Institute of Materials Science and Engineering, National Taiwan University, Taipei, Taiwan, Republic of China |
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Abstract: | In this work, the effects of retained austenite on the hydrogen content and the effective hydrogen diffusivity of an otherwise
fully martensitic structure have been studied. In the electrochemical permeation experiment, the results on the first permeation
transient indicate that high-carbon as-quenched specimens have a lower effective diffusivity than those with an additional
subzero treatment. This was due to the presence of retained austenite in the former specimens, which afforded more sites for
hydrogen trapping throughout the specimen membrane, hence lowering the hydrogen diffusion during the first transient. As the
hydrogen traps were filled up, however, the second permeation transients gave similar effective diffusivity for both as-quenched
and quenched + subzero-treated specimens. After hydrogen charging in hydrogen sulfide solution, the hydrogen contents of the
specimens were determined using the vacuum hot extraction method. The results show that the hydrogen contents of as-quenched
specimens were higher than those of the specimens subjected to quenched + subzero treatment. This again was due to the existence
of retained austenite in as-quenched martensitic matrix, where the interfaces between the retained austenite and martensitic
plates provided extra sites for hydrogen trapping. The hydrogen content of the presenting retained austenite in the martensite
was independent of the carbon content of the specimen, but only depended on the hydrogen-charging period. |
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