An iron oxide -copper bismuth oxide photoelectrochemical cell for spontaneous water splitting |
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Authors: | Chun Du Jie Yang Jinhui Yang Yunkun Zhao Rong Chen Bin Shan |
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Affiliation: | 1. State Key Laboratory of Materials Processing & Die and Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, Hubei, 430074, People''s Republic of China;2. State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metal, Kunming Institute of Precious Metals, Kunming 650106, Yunnan, China;3. State Key Laboratory of Digital Manufacturing Equipment and Technology, School of Mechanical Science and Engineering, Huazhong University of Science and Technology, Wuhan, Hubei, 430074, People''s Republic of China;4. School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan, Hubei, 430074, People''s Republic of China |
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Abstract: | Highly efficient water splitting reaction on hematite photoelectrode has been encumbered by its low photovoltage and photocurrent in a water splitting cell. In this work, a nanostructured hematite photoanode was prepared via a hydrothermal method, and its water oxidation activity was greatly enhanced by the synergetic application of uniform in-situ cobalt-doping and surface modification with fine cobalt iron oxide nanoparticles electrocatalyst. As a result, its remarkable low onset potential of 0.55 VRHE for water oxidation allows the construction of tandem cell with a novel metal oxide photocathode CuBi2O4, which has already proven reasonably robust photoactivity for water reduction reaction. The photocurrent and long-term stability of this metal oxides based device in alkaline electrolyte for unassisted overall water splitting reaction were investigated. A solar to hydrogen efficiency of 0.15% was measured accordingly on this spontaneous hydrogen production device, without the involvement of precious metal components. |
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Keywords: | Hematite photoanode In-situ doping Surface modification Photoelectrochemical water splitting |
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