| 可聚合乳化剂制备高固含量丙烯酸酯乳液 |
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| 引用本文： | 蔡婷,艾照全,鲁艳.可聚合乳化剂制备高固含量丙烯酸酯乳液[J].粘接,2012(10):64-66. |
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| 作者姓名： | 蔡婷 艾照全 鲁艳 |
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| 作者单位： | 有机功能分子合成与应用教育部重点实验室,湖北大学化学化工学院,湖北武汉430062 |
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| 摘 要： | 以甲基丙烯酸甲酯(MMA)为硬单体、丙烯酸丁酯(BA)为软单体、丙烯酸(AA)和N-羟甲基丙烯酰胺(NMA)为功能性单体以及过硫酸铵(APS)为引发剂,合成了固含量为41%左右的丙烯酸酯乳液。研究结果表明,可聚合乳化剂(F-6)、NMA和反应温度等对丙烯酸酯乳液性能有影响。当反应温度为85℃左右、F-6用量为0.5%和NMA用量为0.25%时,合成的丙烯酸酯乳液的综合性能较好。
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| 关 键 词： | 可聚合乳化剂 丙烯酸酯 乳液 |
Preparation of high solid content acrylates emulsion by polymerisable emulsit~ers |
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| CAI Ting
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AI Zhao-quan
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LU Yan.Preparation of high solid content acrylates emulsion by polymerisable emulsit~ers[J].Adhesion in China,2012(10):64-66. |
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| Authors: | CAI Ting AI Zhao-quan LU Yan |
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| Affiliation: | (Key Laboratory for Synthesis and Application of Organic Functional Molecules of Ministry of Education, Faculty of Chemistry and Engineering,Hubei University,Wuhan,Hubei 430062,China) |
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| Abstract: | Using methyl methacrylate （MMA） as the hard monomer,butyl acrylate （BA） as the soft monomer,acrylic acid （AA） and N-hydroxymethyl acrylamide （NMA） as the functional monomers,and ammonium persulfate （APS） as the initiator,the acrylate emulsion with about 41% of solid content was synthctized.The research results showed that the some factors including polymerisable emulsifier （F-6）,NMA and reaction temperature have influence on the performance of acrylate emulsion.The combination properties of acrylate emulsion were better when the reaction temperature was about 85 ℃,the mass fractions ofF-6 and NMA were 0.5% and 0.25%,respectively. |
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| Keywords: | polymerisable emulsifier acrylate emulsion |
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