Charge transport in silver chalcogenides in the region of phase transition

Data on the σ(T), R(T), and U(T) dependences in Ag₂Te, Ag₂Se, and Ag₂S in the region of the phase transition are analyzed. It is found that the phase transition in Ag₂Te is accompanied by a decrease in the electron concentration and this transition in Ag₂Se is accompanied by an increase in this concentration. The concentration of intrinsic charge carriers in Ag₂Te decreases by a factor of 4 as a result of the phase transition and increases by a factor of 2 in Ag₂Se. The effect of variation in the energy-band parameters in the region of phase transition on the electron mobility is considered. It is established that, in Ag₂Te and Ag₂S, electrons are scattered by optical phonons in the region of the phase transition, while electrons are scattered by acoustic phonons in the α and β phases. It is assumed that the anomalously large increase in σ and U in Ag₂S as a result of the phase transition is caused by an increase in the concentration n and a simultaneous decrease in σ _g and m _n ^* by a factor of about 2.