A study of phase stability and mechanical properties of hydroxylapatite–nanosize α-alumina composites

Hydroxylapatite (HA)–nanosize alumina composites were synthesized to study their phase stability and mechanical properties. To make these composites, nanosize α-Al₂O₃ powder was used because of its better sinterability and densification as compared to nanosize γ-Al₂O₃. The composites were air sintered without pressure and hot pressed in vacuum at 1100 °C and 1200 °C. In the composites, HA decomposed to tri-calcium phosphate faster after the air sintering than hot pressing. Moreover, hexagonal unit cell volume of HA left in the composites showed that there was more decomposition of HA after the air sintering than hot pressing. It also showed that HA in the composites was OH^? and Ca²⁺ deficient. As the amount of alumina increased, sinterability considerably decreased. Hot pressing at 1200 °C resulted in better mechanical properties (μ-hardness and fracture toughness) than the hot pressing at 1100 °C.