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THE SYSTEM MAGNESIUM OXIDE-BORIC OXIDE*
Authors:H M Davis  M A Knight
Affiliation:1. School of Mineral Industries The Pensylvania State College State College, Pennsylvania

Assistant Professor of Metallurgy, The Pennsylvania State College, State College, Pa.;2. School of Mineral Industries The Pensylvania State College State College, Pennsylvania

Research Associate, Preston Laboratories, Butler, Pa., formerly Graduate Fellow, Department of Ceramics, The Pennsylvania State College, State College, Pa.

Abstract:Equilibrium In the system has been investigated for compositions from 0.6 to 75 weight per cent MgO. Three intermediate compounds are present. MgO?B2O3 melts incongruently at 988°C. to form 2MgO?B2O3 and a liquid containing more than 99% B2O3. The other two compounds melt congruently: 2MgO?B2O3 at 1340°C. and 3MgO?-B2O3 at 1366°C. At 1142°C., a region of liquid immiscibility extends from 0.6 to 36.0% MgO. Temperatures are accurate within =5°C. Conflicts between these results and those of Toropov and Konovalov (see footnote 8) are discussed.
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