| Al—Ni配比对镍体系催化丁二烯聚合动力学的影响 |
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| 引用本文： | 王光信,高继全,陈滇宝,赵季若,唐学明. Al—Ni配比对镍体系催化丁二烯聚合动力学的影响[J]. 青岛科技大学学报(自然科学版), 1988, 0(2) |
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| 作者姓名： | 王光信 高继全 陈滇宝 赵季若 唐学明 |
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| 作者单位： | 青岛化工学院化工系，青岛化工学院化工系，青岛化工学院高材系 |
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| 摘 要： | 本工作研究了Al—Ni配比对环烷酸镍、三异丁基铝和三氟化硼乙醚络合物体系催化丁二烯聚合动力学参数的影响,证实了聚合过程中催化活性中心镍的价态为Ni(0)和Ni(Ⅰ)。
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| 关 键 词： | 丁二烯 聚合 动力学 |
The Effect of Molar Ratio of Al an Ni on Kinetics of Butadiene Polymerization with Nickel Catalyst System |
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| Wang Guangxin Gao Jiguan. The Effect of Molar Ratio of Al an Ni on Kinetics of Butadiene Polymerization with Nickel Catalyst System[J]. Journal of Qingdao University of Science and Technology:Natutral Science Edition, 1988, 0(2) |
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| Authors: | Wang Guangxin Gao Jiguan |
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| Affiliation: | Wang Guangxin Gao Jiguan (Department of Chemical Engineering)Chen Dianbao Zhao Jiruo Tang Xueming (Department of Polymer Mater ial Engineering) |
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| Abstract: | In this work the effect of molar ratio of Al and Ni on kinetics of butadiene polymerization with the catalyst system Consisting of nickel cycloalkanecabolate, aluminium tri—isobutyl and complex of boron fluoride and ether has been studied. And it has been verified that the active centres of the Catalyst used in this reaction are in the states of Ni(0)and Ni(Ⅰ). |
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| Keywords: | butadiene polymerization kinetics |
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