Effect of substituents in the manganese μ-oxo porphyrins catalyzed oxidation of cyclooctane with molecular oxygen |
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Authors: | J Potowicz E Tabor K Pamin J Haber |
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Affiliation: | aInstitute of Catalysis and Surface Chemistry, Polish Academy of Sciences, ul.Niezapominajek 8, 30-239 Kraków, Poland |
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Abstract: | Electron-donating or electron-withdrawing substituents at the porphyrin rings considerably increase the catalytic activity of the manganese monomeric and μ-oxo porphyrins in the oxidation of cyclooctane with molecular oxygen without the use of sacrificial co-reductant. The change in the catalytic activity is due to the nature and number of the substituents in the porphyrin ring. |
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Keywords: | Metalloporphyrins μ -oxo metalloporphyrins Cyclooctane oxidation |
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