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五种卷烟纸助剂热裂解产物分析
引用本文:黄海群,杨绍文,李庚,朱东来,沈靖轩,肖维毅.五种卷烟纸助剂热裂解产物分析[J].应用化工,2009,28(2).
作者姓名:黄海群  杨绍文  李庚  朱东来  沈靖轩  肖维毅
作者单位:1. 云南瑞升烟草技术,集团,有限公司,云南,昆明,650106
2. 红云烟草,集团,有限责任公司,云南,昆明,650202
摘    要:对5种卷烟纸助剂在300,600,900℃的空气环境中进行热裂解,并对其裂解产物进行了对比分析。结果表明,5种卷烟纸助剂在不同温度条件下的主要裂解产物为醛酮、呋喃类、稠环芳烃类化合物。5种卷烟纸助剂的裂解产物种类也存在一定差异:柠檬酸镁、柠檬酸钙和柠檬酸锌在600℃和900℃条件下产生刺激性很大的丙烯醛物质;柠檬酸钙在热解过程中产生有刺激性的乙酸;柠檬酸镁、柠檬酸锌在热解过程中产生杂环类香味物质。

关 键 词:卷烟纸  助剂  热裂解

Analysis of the thermal crackate of five accessory ingredients
HUANG Hai-qun,YANG Shao-wen,LI Geng,ZHU Dong-lai,SHEN Jing-xuan,XIAO Wei-yi.Analysis of the thermal crackate of five accessory ingredients[J].Applied chemical industry,2009,28(2).
Authors:HUANG Hai-qun  YANG Shao-wen  LI Geng  ZHU Dong-lai  SHEN Jing-xuan  XIAO Wei-yi
Abstract:The five accessory ingredient were pyrolysed at 300,600 and 900 ℃,and comparative analysis of the crackate.The result showed at the different temperature conditions,the major pyrolysates of the five ingredients were aldehyde,ketone,furan and polycyclic aromatic hydrocarbons.There were some differences in crackate of the five ingredient at 600 ℃ and 900 ℃,the crackate of magnesium citrate,calcium citrate and zinc citrate contain acrolein which greated irritation;the crackate of calcium citrate contain acetic acid which greated irritation;the thermal cracking product of magnesium citrate and calcium citrate contain heterocyclic which were good for the smoking flavour.
Keywords:cigarette paper  accessory ingredient  thermal cracking
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