The application of some polydentate Schiff base compounds containing aminic nitrogens as corrosion inhibitors for mild steel in acidic media |
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Authors: | Kaan C Emregül Ece Düzgün Orhan Atakol |
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Affiliation: | Department of Chemistry, Science Faculty, Ankara University, 06100 Tando?an, Ankara, Turkey |
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Abstract: | The effect of three Schiff base compounds namely, (E)-2-(1-(2-(2-hydroxyethylamino)ethylimino)ethyl)phenol(I), 2,2′-(1E,1′E)-1,1′-(2,2′-azanediylbis(ethane-2,1-diyl)bis(azan-1-yl-1-ylidene))bis(ethan-1-yl-1-ylidene)diphenol(II) and 2,2′-((2E,12E)-3,6,9,12-tetraazatetradeca-2,12-diene-2,13-diyl)diphenol(III) on the corrosion behavior of steel in 2 M HCl solution has been investigated at 298 K by weight loss measurements, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) methods. The inhibition efficiencies obtained from all methods employed are in good agreement. Results show compound III to be the best inhibitor with a mean efficiency of 93% at 10−2 M additive concentration. Studies showed all three compounds to act as mixed type inhibitors and to obey the Langmuir adsorption isotherm. |
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Keywords: | Steel Corrosion Inhibition Polydentate Schiff base compounds |
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