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Corrosion resistance of HVOF-sprayed coatings for hard chrome replacement
Authors:Giovanni Bolelli  Tiziano Manfredini
Affiliation:Dipartimento di Ingegneria dei Materiali e dell’Ambiente, Università di Modena e Reggio Emilia, Via Vignolese 905, 41100 Modena, MO, Italy
Abstract:HVOF-sprayed coatings (WC-17Co, WC-10Co-4Cr, Co-28Mo-17Cr-3Si) and electrolytic hard chrome (EHC) coatings corrosion resistances have been compared through electrochemical polarization tests (0.1 N HCl, 0.1 N HNO3) and Corrodkote test. EHC coatings passivate in HNO3, but undergo pitting corrosion in HCl and in Corrodkote test too. HVOF coatings do not passivate, but possess more noble corrosion potentials. Both in HNO3 and HCl, they undergo more generalized corrosion, with similar icorr; crevice corrosion along splat boundaries is sometimes detected after the HCl test. Their icorr in 0.1 N HCl solution is lower than in several of EHC coatings. No visible damage in the HVOF coatings has occurred after the Corrodkote test.
Keywords:C  Pitting corrosion  B  Polarization  A  Metal matrix composites  B  SEM  C  Acid corrosion
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