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Electrochemical and chemical reactions in baths for plating amorphous alloys
Authors:M. Donten  J. Osteryoung
Affiliation:(1) Department of Chemistry, State University of New York at Buffalo, 14214 Buffalo, New York, USA;(2) Present address: Department of Chemistry, University of Warsaw, ul Pasteura 1, 02093 Warsaw, Poland
Abstract:Deposition of amorphous alloys of (W, Co, B) is accompanied by anodic decomposition of ammonium citrate (pH 8.5) electrolyte. Products of decomposition include amines and nitro-organic compounds. Also some nitrite, and probably nitrate, is found in solutions electrolyzed for a long time. The anodic decomposition processes are catalyzed by cobalt.
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