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二氧化氮消除柴油机排气中炭烟过程基础研究
引用本文:张守臣,赵修仁,刘长厚,陈家骅. 二氧化氮消除柴油机排气中炭烟过程基础研究[J]. 燃烧科学与技术, 2002, 8(2): 163-165
作者姓名:张守臣  赵修仁  刘长厚  陈家骅
作者单位:1. 大连理工大学化工学院,大连,116012
2. 大连理工大学内燃机研究所,大连,116023
基金项目:清华大学汽车安全与节能国家重点实验室学基金项目。
摘    要:用热重法对柴油机排气中的炭烟与NO2的反应性能进行了研究,考察了反应温度和NO2浓度对消炭速率的影响,并根据实验数据在NO2气氛下对炭烟的消炭速率进行了反应动力学处理,得到了可用以计算炭烟消炭速率的动力议程与有关的参数。与在氧气气氛下炭烟消炭速率的比较可见,NO2的消炭速率远大于O2。

关 键 词:二氧化氮 柴油机 排气 炭烟过程 热重
文章编号:1006-8740(2002)02-0163-03
修稿时间:2000-12-29

Study on the Cleaning of Diesel Exhaust Particulate by NO2
ZHANG Shou chen ,ZHAO Xiu ren ,LIU Chang hou ,CHEN Jia ha. Study on the Cleaning of Diesel Exhaust Particulate by NO2[J]. Journal of Combustion Science and Technology, 2002, 8(2): 163-165
Authors:ZHANG Shou chen   ZHAO Xiu ren   LIU Chang hou   CHEN Jia ha
Affiliation:ZHANG Shou chen 1,ZHAO Xiu ren 1,LIU Chang hou 1,CHEN Jia ha 2
Abstract:The oxidation reaction of NO 2 and diesel exhaust particulate were studied by means of the thermo gravimetric method in order to study the possibility of cleaning soot particulates in this way.Experiments were carried out at a constant temperature and NO 2 concentration,as well as under temperature programmed conditions.Results show that the reaction velocity is increased as the temperature or NO 2 concentration increases.A macro kinetic model for this reaction was assumed according to experimental data,the order of NO 2 concentration is 0.5 and activation energy is 11 972 J/mol.A set of experiments were carried out for the purpose of comparing the oxidation abilities of O 2 and NO 2,results show that NO 2 has higher oxidation ability than O 2 has.
Keywords:NO 2  diesel exhaust  thermo gravimetric  particulate
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