Investigation on molar heat capacity,standard molar enthalpy of combustion for guaiacol and acetyl guaiacol ester |
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Authors: | Changshuai Shen Wenli Li Cairong Zhou |
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Affiliation: | School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, China |
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Abstract: | The molar heat capacities (Cp) of guaiacol (CAS 90-50-1) and acetyl guaiacol ester (AGE, CAS 613-70-7) were determinated from 290 K to 350 K by differential scanning calorimetry (DSC), and expressed as a function of temperature. Two kinds of group contribution models were used to estimate the molar heat capacities of both guaiacol and AGE, the average relative deviation is less than 10%. The standard molar enthalpies of combustion of guaiacol and AGE were -3590.0 kJ·mol-1 and -4522.1 kJ·mol-1 by a precise thermal isolation Oxygen Bomb Calorimeter. The standard molar enthalpies of formation of guaiacol and AGE in a liquid state at 298.15 K were calculated to be -307.95 kJ·mol-1 and -448.72 kJ·mol-1, respectively, based on the standard molar enthalpies of combustion. The thermodynamic properties are useful for exploiting the new synthesis method, engineering design and industry production of AGE using guaiacol as a raw material. |
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Keywords: | Guaiacol Acetyl guaiacol ester (AGE) Molar heat capacity Standard molar enthalpy of combustion |
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