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| Crystal Structure and Spectrum Character of Bis[1-(4-Methoxyphenyl)-3-(1H-1,2,4-Triazol-1-yl)-1-Propanone] dichorozinc(Ⅱ) Complex | |
| 引用本文： | 曹克广,王忠卫,孙成辉,赵信岐.Crystal Structure and Spectrum Character of Bis[1-(4-Methoxyphenyl)-3-(1H-1,2,4-Triazol-1-yl)-1-Propanone] dichorozinc(Ⅱ) Complex[J].北京理工大学学报(英文版),2005,14(4):425-428. |
| 作者姓名： | 曹克广 王忠卫 孙成辉 赵信岐 |
| 作者单位： | School of Material Science and Engineering Beijing Institute of Technology Beijing100081 China，Chengde Petroleum College Chengde067000 China，School of Chemical and Environment Engineering Shandong University of Science and Technology Qingdao266510 China，School of Material Science and Engineering Beijing Institute of Technology Beijing100081 China，School of Material Science and Engineering Beijing Institute of Technology Beijing100081 China |
| 基金项目： | Sponsored by the Natural Science Foundation of Hebei Province （205403） |
| 摘 要： | The titled new complex was synthesized and determined by X-ray diffraction. The crystal belongs to monoclinic, P-1 group, a=1.899 7(4) nm, b=0.581 07(12) nm, c=2.420 9(5) nm, β=90.65(3)°, V=2.672 2(9) nm~3, Z=4, D_c=1.488 g/cm~3. It has C_2 symmetry with the axis through the Zn atom, and the zinc atom is coordinated by two N atoms of the 1-(4-methoxyphenyl)-3-(1H-1,2,4-triazol-1-yl)-1-propanone ligands and two Cl~- atoms, forming a slightly distorted tetrahedron. Intermolecular hydrogen bonds make the complex stable. IR and electronic spectra study of the target complex were also carried. |
| 关 键 词： | 晶体结构 光谱特性 UV-vis光谱 光谱分析 |
| 文章编号： | 1004-0579（2005）04-0425-04 |
| 收稿时间： | 2004-03-17 |
Crystal Structure and Spectrum Character of Bis[1-(4-Methoxyphenyl)-3-(1H-1,2,4-Triazol-1-yl)-1-Propanone] dichorozinc( Ⅱ ) Complex |
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| CAO Ke-guang,WANG Zhong-wei,SUN Cheng-hui and ZHAO Xin-qi.Crystal Structure and Spectrum Character of Bis[1-(4-Methoxyphenyl)-3-(1H-1,2,4-Triazol-1-yl)-1-Propanone] dichorozinc( Ⅱ ) Complex[J].Journal of Beijing Institute of Technology,2005,14(4):425-428. | |
| Authors: | CAO Ke-guang WANG Zhong-wei SUN Cheng-hui and ZHAO Xin-qi |
| Affiliation: | 1. School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China;Chengde Petroleum College, Chengde 067000, China 2. School of Chemical and Environment Engineering, Shandong University of Science and Technology, Qingdao 266510,China 3. School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China |
| Abstract: | The titled new complex was synthesized and determined by X-ray diffraction. The crystal belongs to monoclinic, P-1 group, a=1.899 7(4)nm, b=0.581 07(12)nm, c=2.420 9(5)nm, β=90.65(3)°,V= 2.672 2(9) nm3, Z = 4, Dc= 1.488 g/cm3. It has C2 symmetry with the axis through the Zn atom,and the zinc atom is coordinated by two N atoms of the 1-(4-methoxyphenyl)-3-(1H-1, 2, 4-triazol-1-yl)-1-propanone ligands and two Cl- atoms, forming a slightly distorted tetrahedron. Intermolecular hydrogen bonds make the complex stable. IR and electronic spectra study of the target complex were also carried. |
| Keywords: | 1H-1 2 4-triazol-1-yl complex crystal structure UV-vis spectrum |
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