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乙烯聚合新工艺及产品特性
引用本文:孟伟娟,张欣,李洪泊,王健,陈标华.乙烯聚合新工艺及产品特性[J].合成树脂及塑料,2011,28(2):1-5.
作者姓名:孟伟娟  张欣  李洪泊  王健  陈标华
作者单位:1. 北京化工大学,化工资源有效利用国家重点实验室,北京,100029;中国石油化工股份有限公司北京北化院燕山分院,北京,102500
2. 中国石油化工股份有限公司北京北化院燕山分院,北京,102500
3. 北京化工大学,化工资源有效利用国家重点实验室,北京,100029
摘    要:采用间歇聚合试验装置模拟了乙烯聚合新工艺(淤浆均聚合-离心分离-气相共聚合)的流程.考察了新工艺的可行性,研究了新工艺的技术特点及产品特性,并将采用新上艺制备的试样与工业生产PE80及PE100级双峰分布聚乙烯进行比较.结果表明:第一段淤浆聚合后脱除溶剂不影响第二段的气相共聚合活性,该工艺是可行的;通过模拟不同的工艺表...

关 键 词:聚乙烯  聚合工艺  相对分子质量及其分布  力学性能

A new ethylene polymerization process and the properties of its products
Meng Weijuan,Zhang Xin,Li Hongbo,Wang Jian,Chen Biaohua.A new ethylene polymerization process and the properties of its products[J].China Synthetic Resin and Plastics,2011,28(2):1-5.
Authors:Meng Weijuan  Zhang Xin  Li Hongbo  Wang Jian  Chen Biaohua
Affiliation:Meng Weijuan1,2,Zhang Xin2,Li Hongbo2,Wang Jian2,Chen Biaohua1(1.State Key Laboratory of Chemical Resource Engineering,Beijing University of Chemical Technology,Beijing 100029,China,2.Yanshan Branch,Beijing Research Institute of Chemical Industry,SINOPEC,Beijing 102500,China)
Abstract:A new ethylene polymerization process(slurry homopolymerization-centrifugation separation-gas phase copolymerization) was simulated in a batch polymerization equipment.The feasibility of the new process was discussed;the technical characteristics of the new process and the properties of the products were studied.The sample prepared with the new process was compared with the commercial bimodal polyethylene products,PE80 and PE100.The results show that the removal of solvent after slurry homopolymerization do...
Keywords:polyethylene  polymerization process  relative molecular mass and its distribution  mechanical property  
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