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水辅注射成型聚丙烯制品的取向结晶
引用本文:贾振华,李松伟,刘宪虎,郝晓琼,曹伟,郑国强. 水辅注射成型聚丙烯制品的取向结晶[J]. 合成树脂及塑料, 2011, 28(2): 67-70
作者姓名:贾振华  李松伟  刘宪虎  郝晓琼  曹伟  郑国强
作者单位:郑州大学材料科学与工程学院,国家橡塑模具工程研究中心,河南,郑州,450002
摘    要:应用小角X射线散射研究了水辅注射成型(WAIM)等规聚丙烯制品中串晶(shish-kebab)结构的形成、分布以及片晶取向行为.结果表明:根据取向度不同,WAIM制品沿壁厚方向可明显分为表层、芯层和水道层.表层和水道层均有shish-kebab结构生成,且在表层生成的数量比水道层多,而芯层则没有这种结构.这种shish...

关 键 词:等规聚丙烯  小角X射线散射  水辅注射成型  结晶  取向

Crystalline orientation of the water-assisted injection molded polypropylene
Jia Zhenhua,Li Songwei,Liu Xianhu,Hao Xiaoqiong,Cao Wei,Zheng Guoqiang. Crystalline orientation of the water-assisted injection molded polypropylene[J]. China Synthetic Resin and Plastics, 2011, 28(2): 67-70
Authors:Jia Zhenhua  Li Songwei  Liu Xianhu  Hao Xiaoqiong  Cao Wei  Zheng Guoqiang
Affiliation:Jia Zhenhua,Li Songwei,Liu Xianhu,Hao Xiaoqiong,Cao Wei,Zheng Guoqiang(School of Material Science and Engineering,National Engineering Research Center for Advanced Polymer Processing Technology,Zhengzhou University,Zhengzhou 450002,China)
Abstract:The formation and distribution of shish-kebab structure and the lamellae orientation of the water-assisted injection molded(WAIM) isotactic polypropylene(iPP) part were studied by small-angle X-ray scattering(SAXS).The results indicate that the WAIM part can be divided into three different layers along the wall thickness direction: surface layer,core layer and water channel layer,according to the different degrees of orientation.The shish-kebab structure forms in the surface and water channel layers of the ...
Keywords:isotactic polypropylene  small-angle X-ray scattering  water-assisted injection molding  crystallization  orientation  
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