Alkaline isomerization of methyl crepenynate |
| |
| Authors: | K. L. Mikolajczak M. O. Bagby I. A. Wolff |
| |
| Affiliation: | (1) Northern Regional Research Laboratory, Peoria, Illinois |
| |
| Abstract: | Methyl crepenynate (methyl-cis-9-octadecen-12-ynoate) is readily isomerized by potassium hydroxide in ethylene glycol to an 8,10,12-octadecatrienoic acid in good yield. A reaction carried out at 120C for 1 hr in 10% base is sufficient to convert the nonconjugated enyne system completely to conjugated triene systems. Presented at AOCS Meeting in New Orleans, 1964. A laboratory of the No. Utiliz. Res. & Der. Div., ARS, USDA. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
