OPTIMAL DISTRIBUTION OF MULTIFUNCTIONAL CATALYSTS IN A PACKED BED REACTOR |
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Authors: | J Scott Buchanan Sankaran Sundaresan |
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Affiliation: |
a Department of Chemical Engineering, Princeton University, Princeton, NJ |
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Abstract: | The problem of the optimal distribution of two multifunctional catalysts is analyzed. Two methods for obtaining optimal catalyst profiles, an analytic-numeric method and the method of steepest ascent, are compared. Though the analytic-numeric method yields a more accurate solution, the method of steepest ascent is usually easier to apply. Optimal catalyst loading profiles are determined for two cases of commercial interest: selective oxidation of butene and naphtha reforming with bimetallic catalysts- A sequential loading of the bismuth molybdate and the vanadium phosphate catalysis is recommended for low butene concentration levels, while at higher butene levels a mixed loading of the two catalysts may be desirable. For commonly encountered naphtha feedstocks a sequential loading of the Pt-Re and the Pt-Ir catalysts tends to be optimal. These compare well with experimental evidence in the literature. |
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Keywords: | Catalyst distribution Reactor loading Multifunctional catalysts Optimization |
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