Interaction of radiation-induced defects of glasses with CdSe and CdS nanocrystals |
| |
Authors: | S L Kraevskii V F Solinov |
| |
Affiliation: | (1) Research Institute of Technical Glass, ul. Krzhizhanovskogo 29, 117218 Moscow, Russia |
| |
Abstract: | The influence of X-ray irradiation on the absorption spectra of commercial light filters based on the glasses containing selenium,
cadmium, and sulfur has been investigated. The light filters were preliminary subjected to the heat treatment, which resulted
in the precipitation of nanocrystals in the glass matrix. The irradiation leads to stationary partial bleaching of glasses.
Analysis demonstrates that the difference spectra contain the induced absorption bands of conventional radiation-induced color
centers of alkali silicate glasses and a fine structure. The fine structure closely resembles the known difference spectra
obtained under the action of the external constant or low-frequency alternating electric field on glasses containing CdSe
nanocrystals. The conclusion is drawn that the stable radiation-induced centers of the glass at the interface with nanocrystals
serve as a source of the Coulomb field affecting the energy levels of the size quantization of the nanocrystals. It is suggested
that nanocrystals of the type of the CdSxS1−x solid solutions in these glasses are either lacking or do not manifest themselves in the spectra after irradiation. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|