| 原料对LiCo0.05Mn1．95O4晶体结构及性能的影响 |
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| 引用本文： | 宝冬梅,肖寒,邹光龙.原料对LiCo0.05Mn1．95O4晶体结构及性能的影响[J].电池工业,2008,13(6):377-380. |
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| 作者姓名： | 宝冬梅 肖寒 邹光龙 |
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| 作者单位： | 贵州民族学院化学与环境科学学院 |
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| 摘 要： | 采用高温固相法，用不同的锂源（LiNO3、Li2CO3、LiOH·H2O）和不同锰源（CMD、MnCO3、Mn（Ac）2·4H2O、EMD）分别合成了LiCo0.05Mn1.95O4样品，并结合XRD、SEM和电化学性能测试等手段，研究了不同合成原料对锂离子电池正极材料LiCo0.05Mn1.95O4的晶体结构、外观形貌和电化学性能的影响。研究结果表明：LiOH·H2O和EMD是较好的合成LiCo0.05Mn1.96O4的材料。
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| 关 键 词： | 锂离子电池 LiCo0.05Mn1.95O4 晶体结构 电化学性能 |
Effects of raw materials on crystalline structure and electrochemical properties of LiCo0.05Mn1.95O4 |
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| BAO Dong-mei,XIAO Han,ZOU Guang-long.Effects of raw materials on crystalline structure and electrochemical properties of LiCo0.05Mn1.95O4[J].Chinese Battery Industry,2008,13(6):377-380. |
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| Authors: | BAO Dong-mei XIAO Han ZOU Guang-long |
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| Affiliation: | (College of Chemistry and Environmental Science, Guizhou University for Nationalities, Guiyang, Guizhou 550001, China) |
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| Abstract: | Different samples like LiCo0.05Mn1.95O4 were synthesized by different raw materials containing Li and Mn, such as LiNO3.Li2CO3.LiOH·H2O、CMD、MnCO3.Mn （Ac）2·4H2O and EMD . With the analysis of XRD, SEM and electrochemical properties, the effects of different raw materials on crystalline structure, shapes and electrochemical properties of LiCo0.05Mn1.95O4 for Li-ion battery cathode materials were discussed in this paper. The experimental results showed that, LiOH·H2O and EMD were the better materials to synthesize LiCo0.05Mn1.95O4. |
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| Keywords: | LiCo0 05Mn1 95O4 |
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