Characterization of new FIR laser lines from CD3-rockingand asymmetric CD3 deformation modes of 13CD3OD

In this paper, we report new optically pumped far-infrared (FIR) laser lines from the in-plane CD₃-rocking and asymmetric CD ₃ deformation absorption vibrational bands of ¹³CD ₃OD. A waveguide CO₂ laser of wide tunability (290 MHz) was used as the pump source, and a Fabry-Perot open cavity as the FIR laser resonator. Optoacoustic absorption spectrum was used as a guide to search for new FIR laser lines. We could observe 13 new laser lines in the range 103-491 μm. The lines were characterized according to wavelength, relative polarization, relative intensity, and optimum working pressure. The transferred lamb-dip technique was used to measure the frequency absorption transition for both new and previously reported laser lines