| TATBIW与TADBIW的氢解反应特性 |
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| 引用本文： | 韩卫荣,欧育湘,张雪红,黄兴,牟微,高岩磊. TATBIW与TADBIW的氢解反应特性[J]. 含能材料, 2008, 16(2): 153-155 |
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| 作者姓名： | 韩卫荣 欧育湘 张雪红 黄兴 牟微 高岩磊 |
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| 作者单位： | 石家庄学院化工学院,河北,石家庄,050035;北京理工大学材料科学与工程学院,北京,100081 |
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| 摘 要： | 研究了六苄基六氮杂异伍兹烷 (HBIW) 的氢解不完全产物三乙酰基三苄基六氮杂异伍兹烷(TATBIW)对氢解产品四乙酰基二苄基六氮杂异伍兹烷(TADBIW)的二次氢解反应产生的影响.结果表明,TATBIW较TADBIW稳定性差,在甲酸介质中易于破笼,且易引起二次氢解催化剂中毒;但当催化剂用量加大到1%时,仍可得到TATBIW氢解完全的产物三乙酰基三甲酰基六氮杂异伍兹烷(TATFIW).
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| 关 键 词： | 有机化学 四乙酰基二苄基六氮杂异伍兹烷(TADBIW) 三乙酰基三苄基六氮杂异伍兹烷(TATBIW) 氢解 催化剂 |
| 文章编号： | 1006-9941(2008)02-0153-03 |
| 收稿时间： | 2007-04-04 |
| 修稿时间： | 2007-04-04 |
Hydrogenolysis of Triacetyltribenzylhexaazaisowurtzitaneand Tetraacetyldibenzylhexaazaisowurtzitane |
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| HAN Wei-rong,OU Yu-xiang,ZHANG Xue-hong,HUANG Xing,MOU Wei and GAO Yan-lei. Hydrogenolysis of Triacetyltribenzylhexaazaisowurtzitaneand Tetraacetyldibenzylhexaazaisowurtzitane[J]. Chinese Journal of Energetic Materials, 2008, 16(2): 153-155 |
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| Authors: | HAN Wei-rong OU Yu-xiang ZHANG Xue-hong HUANG Xing MOU Wei GAO Yan-lei |
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| Abstract: | Tetraacetyldibenzylhexaazaisowutzitane (TADBIW) was the debenzylation compound of hydrogenolysis of hexabenzylhexaazaisowurtzitane (HBIW). Triacetyltribenzylhexaazaisowurtzitane (TATBIW) was the partial debenzylation compound of hydrogenolysis of HBIW. The influence of TATBIW on the hydrogenolysis of TADBIW were studied. Results show that TATBIW is less stable than TADBIW and easily decomposes in formic acid, and its by-products inhibit the hydrogenolysis of TATBIW. The amount of catalyst is increased to 1%, the final product triacetyltriformylhexaazaisowurtzitane (TATFIW) is obtained. |
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