| 载邻菲罗林配体的三维有序大孔聚苯乙烯材料的制备及表征 |
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| 引用本文： | 杨惠芳,王燕燕,刘宾元,张旭,刘盘阁,闫卫东.载邻菲罗林配体的三维有序大孔聚苯乙烯材料的制备及表征[J].高分子材料科学与工程,2010(3):123-126. |
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| 作者姓名： | 杨惠芳 王燕燕 刘宾元 张旭 刘盘阁 闫卫东 |
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| 作者单位： | 河北工业大学高分子科学与工程研究所;石家庄铁道学院材料学院; |
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| 基金项目： | 国家自然科学基金面上项目(50273009);;河北省自然科学基金(E2007000052);;教育部功能高分子材料重点实验室开放基金(2006-007);;河北省教育厅科研计划项目(2007307) |
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| 摘 要： | 采用胶体晶模板法合成了结构规整的三维有序聚合物材料,并在孔壁上引入了氯甲基。以氯甲基化的孔材料为基础进一步将含双齿N的邻菲罗林配体引到孔壁上,实现了聚合物孔材料的功能化,并通过扫描电镜(SEM),红外光谱(FT-IR)及热失重对各步所得产物进行表征。结果表明,成功将邻菲罗林配体负载到孔内,功能化后的孔材料很好地保持了三维有序大孔材料的结构特征,且孔材料在200℃左右呈现较好的耐热性。
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| 关 键 词： | 三维有序大孔材料 聚苯乙烯 氯甲基化 邻菲罗林 功能化 |
Preparation and Characterization of Three-Dimensionally Ordered Macroporous Polystyrene Functionalized with 1,10-Phenanthroline |
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| YANG Hui-fang,WANG Yan-yan,LIU Bin-yuan,ZHANG Xu,LIU Pan-ge,YAN Wei-dong.Preparation and Characterization of Three-Dimensionally Ordered Macroporous Polystyrene Functionalized with 1,10-Phenanthroline[J].Polymer Materials Science & Engineering,2010(3):123-126. |
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| Authors: | YANG Hui-fang WANG Yan-yan LIU Bin-yuan ZHANG Xu LIU Pan-ge YAN Wei-dong |
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| Affiliation: | 1.Institute of Polymer Science and Engineering;Hebei University of Technology;Tianjin 300130;China;2.School of Material;Shijiazhuang Railway Institute;Shijiazhuang 050043;China |
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| Abstract: | Three-dimensionally ordered macroporous polystyrenes were prepared via SiO2 template approach.The pores were functionalized by chloromethylation,then the bidentate ligand(1,10-phenanthrolin)was anchored by means of functional group transformation.The ordered macroporous materials were characterized by scanning electron microscope(SEM),infrared spectroscopic(IR),and thermogravimetry analysis(TG).The results reveal that the pores are successfully bonded with 1,10-phenanthroline and the original morphology of ... |
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| Keywords: | three-dimensionally ordered macroporous materials polystyrene chloromethylation 1 10-phenanthroline functionalization |
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