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新型非线性光学晶体Ca4RO(BO3)3的研究进展
引用本文:罗军,钟真武,范世Ji,王锦昌.新型非线性光学晶体Ca4RO(BO3)3的研究进展[J].无机材料学报,2000,15(1):1-8.
作者姓名:罗军  钟真武  范世Ji  王锦昌
作者单位:中国科学院上海硅酸盐研究所,上海200050
摘    要:作为新型非线性光学材料,钙-稀土硼酸盐晶体Ca4RO(BO3)3(R-La^3+、Nd^3+、Sm^3+、Gd^3+、Y^3+、Er^3+、Tb^3+、Lu^3+)近来引起了广泛的重视,该系列晶体属非中心对称的单斜晶系,空间群Cm。本文综术字上述晶体的结构和生长研究的进展,总结了晶体的线性光学/非线性光学性能以及要晶体的激光自倍频性能,指出这些晶体在非线性光学领域潜在的应用前景。

关 键 词:CaRO(BO3)3  非线性光学晶体  晶体生长  频率变换
收稿时间:1999-3-12
修稿时间::

Progress of Research on New Nonlinear Optical Crystals Ca4RO(BO3)3
LUO Jun,ZHONG Zhen-Wu,FAN Shi-Ji,WANG Jin-Chang.Progress of Research on New Nonlinear Optical Crystals Ca4RO(BO3)3[J].Journal of Inorganic Materials,2000,15(1):1-8.
Authors:LUO Jun  ZHONG Zhen-Wu  FAN Shi-Ji  WANG Jin-Chang
Affiliation:ShanghaiInstituteofceramics;ChineseAcademyofSciences;Shanghai200050;China
Abstract:The isostructural calcium rare-earth oxyborates Ca4RO(BO3)3(R---La3+, Nd3+, Sm3+, Gd3+, Y3+, Er3+, Tb3+, Lu3+) as nonlinear optical materials have attracted great attentions recently. They belong to the monoclinic crystallographic system with space group Cm. The progress on the research of their structures and crystal growth was reviewed, and their linear/nonlinear optical properties and self-frequency doubling properties were also summarized in detail. It was suggested that these crystals possess potential applications in frequency conversion.
Keywords:Ca4RO(BO3)3(R-Rare-earth)  nonlinear optical crystal  crystal growth  frequency conversion
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