Fischer-Tropsch synthesis with an iron catalyst: Incorporation of ethene into higher carbon number alkanes期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Fischer-Tropsch synthesis with an iron catalyst: Incorporation of ethene into higher carbon number alkanes

Authors:	Li -Min Tau Hossein A. Dabbagh Birbal Chawla Burtron H. Davis

Affiliation:	(1) Center for Applied Energy Research, University of Kentucky, 3572 Iron Works Pike, 40511-8433 Lexington, KY, USA;(2) Present address: Paulsboro Research Laboratory, Mobil Research and Development Inc., 08066 Paulsboro, NJ, USA

Abstract:	Tracer studies with C labeled ethene show that for synthesis over a doubly promoted iron catalyst at 7 atm and ca. 60% CO conversion, higher carbon number products are formed from ethene initiation. About 10% of the added ethene (ethene/CO 0.02) is incorporated into C₅⁺ products and that ca. 85% of the ethene that is incorporated does so by initiating chain growth.

Keywords:	Fischer-Tropsch synthesis iron catalyst tracer studies ¹⁴C labeled ethene alkenes chain growth radioactivity
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