首页 | 本学科首页   官方微博 | 高级检索  
     

聚丙烯(PP)/黏土复合材料熔融剂的研究
引用本文:诸昌武,王卫霞.聚丙烯(PP)/黏土复合材料熔融剂的研究[J].山西化工,2013(4):11-14.
作者姓名:诸昌武  王卫霞
作者单位:扬州工业职业技术学院
摘    要:以马来酸酐(MAH)等为单体接枝聚丙烯作为聚丙烯(PP)/黏土复合材料熔融剂,考察了马来酸酐用量、引发剂过氧化苯甲酰(BPO)用量、反应时间、温度等因素对产物接枝率的影响,并通过红外光谱图对PP-g-MAH进行表征。结果表明,当m(PP):m(复配单体):m(BPO)=10.0:2.0:0.6、反应温度控制在120℃左右、复配单体为马来酸酐/苯乙烯时,熔融剂PP-g-MAH的接枝率可获得较大值3.9%。实验同时表明,反应时间对接枝率的影响不大;苯乙烯的加入对接枝率有较大的影响,与普通单体单一马来酸酐相比,加入苯乙烯的接枝率明显提高。

关 键 词:聚丙烯  马来酸酐  接枝  熔融剂

Studies on the melting agent for polypropylene and clunch composite
ZHU Chang-wu;WANG Wei-xia.Studies on the melting agent for polypropylene and clunch composite[J].Shanxi Chemical Industry,2013(4):11-14.
Authors:ZHU Chang-wu;WANG Wei-xia
Affiliation:ZHU Chang-wu;WANG Wei-xia;Yangzhou Polytechnic Institute;
Abstract::The monomer of MAH is grafted polypropylene as the melting agent for polypropylene / clunch composite. Discuss the influ- ence of the MAH and BPO dosage, reaction time, temperature on the grafting rate, The PP-g-MAH was characterized by infrared spec-tra. The results show that : when the m(PP) : mixed monomer) : m(BPO) = 10: 2: 0.6, the reaction temperature is 120 ℃, the mixed monomer are maleic anhydride / styrene, the graft melting agent PP-g-MAH rate can obtain a larger value of 3.9%. The reaction timehas little effect on the rate of graft. Styrene has great effect on the grafting rate. Compared styrene, with the ordinary single monomer maleic anhydride grafted, the graft rate increased.
Keywords:polypropylene  MAH  graft  melting agent
本文献已被 CNKI 维普 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号