| 水扬酸镍的合成表征及结构分析 |
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| 引用本文： | 刘卫兵,李良超.水扬酸镍的合成表征及结构分析[J].精细化工中间体,2002,32(4):44-45. |
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| 作者姓名： | 刘卫兵 李良超 |
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| 作者单位： | 1. 楚源集团华丽染料公司,湖北,石首,434400
2. 荆州师范学院化学系,湖北,荆州,434100 |
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| 基金项目： | 湖北省教育厅自然科学基金资助课题 (99C0 69) |
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| 摘 要： | 用流变相反应法合成了Ni(OH)Sal·H2 O和Ni2 (OH) 2 Sal2 ·H2 O。通过元素分析、TG、IR、XRD和磁矩对其结构进行了分析。结果表明两个配合物都属于单斜晶系 ,其晶胞参数为 ,Ni(OH)Sal·H2 O∶a =13.1179,b =11.36 41,c =9.5 6 0 5 ,β =92 .96 2 ,V =14 2 3.31(97) 3,Z =7,Dcalcd .=1.885 g/cm3,Dexpt=1.85 8g/cm3;Ni2 (OH) 2 Sal2 ·H2 O :a =13.12 17,b =11.35 80 ,c =9.5 5 2 2 ,β =92 .978 ,V =14 2 1.72 (95 ) 3,Z =4 ,Dcalc=2 .0 73g/cm3,Dexp=2 .0 0 0 g/cm3。
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| 关 键 词： | 水杨酸镍 流变态 合成 结构分析 |
| 文章编号： | 1009-9212(2002)04-0044-02 |
| 修稿时间： | 2002年7月20日 |
The Rheological State Synthesis and Characterization and Structural Analysis of Nickel Monosalicylates |
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| LIU Wei bing,LI Liang chao..The Rheological State Synthesis and Characterization and Structural Analysis of Nickel Monosalicylates[J].Fine Chemical Intermediates,2002,32(4):44-45. |
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| Authors: | LIU Wei bing LI Liang chao |
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| Abstract: | Nickel monosalicylates Ni(OH)(C 6H 4OHCO 2)·H 2O(A) and Ni 2(OH) 2(C 6H 4OHCO 2) 2·H 2O(B)] were synthesized through the rheological phase reaction method.Their structure was characterized by elemental analysis,IR,TG,X ray power diffraction and magnetic moment.XRD indicated that the two complexs are monoclinic crystal system and its crystal cell parameters are respectively,(A)∶a=13.1179,b=11.3634,c=9.5605?,β=92.962,V=1423.31(97)? 3,Z=9,D calcd =1.885g/cm 3,(B)∶a=13.1217,b=11.3580,c=9.5522?,β=92.978,V=1421.72(95)? 3,Z=4,D calcd. =2.072g/cm 3,D expt =2.000g.cm 3. |
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| Keywords: | nickel salicylates rheological phase synthesis structure analysis |
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