| 二茂铁衍生物的化学结构对高氯酸铵燃速的影响 |
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| 引用本文： | 马庆云,梁金鹏. 二茂铁衍生物的化学结构对高氯酸铵燃速的影响[J]. 兵工学报, 1990, 0(1) |
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| 作者姓名： | 马庆云 梁金鹏 |
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| 作者单位： | 北京理工大学(马庆云)，北京理工大学(梁金鹏) |
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| 摘 要： | 本文研究了几种不同化学结构的二茂铁衍生物对高氯酸铵燃烧的催化作用,探讨了它们的化学结构与催化效应之间的关系,给出了燃速压力曲线和热分解温度。得出结论:二茂铁衍生物催化剂分子的空间结构的对称性和取代基的电子效应是影响其催化效率的主要因素。
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| 关 键 词： | 催化剂 催化效果 燃烧速度 |
THE EFFECT OF CHEMICAL STRUCTURE OF FERROCENE DERIVATIVES ON THE BURNING RATE OF AMMONIUM PERCHLORATE |
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| Ma Qingyun Liang Jinpeng. THE EFFECT OF CHEMICAL STRUCTURE OF FERROCENE DERIVATIVES ON THE BURNING RATE OF AMMONIUM PERCHLORATE[J]. Acta Armamentarii, 1990, 0(1) |
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| Authors: | Ma Qingyun Liang Jinpeng |
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| Affiliation: | Beijing Institute of Technology |
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| Abstract: | In the paper is discussed the catalytic effect of some ferrocene derivatives having various chemical structures on the combustion of ammonium perchlorate (AP). Discussed also is the relationship between the chemical structure of ferrocene derivatives and their catalytic effect. Curves of burning rate versus pressure and the thermodecomposition temperature are shown. Conclusion drawn from this discussion is that the chief factors affecting the catalytic effect are the symmetry in the stereo-structure of ferrocene derivative molecules and the electronic effects of the substituent. |
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| Keywords: | catalysts catalytic effects burning rate |
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