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The effect of sputtering power on the structure and photocatalytic activity of TiO2 films prepared by magnetron sputtering
Authors:Baoshun Liu  Qi Hu Liping Wen
Affiliation:a Key Laboratory of Silicate Materials Science and Engineering, Ministry of Education, Wuhan, Hubei 430070, PR China
b School of Material Science and Technology (Wuhan University of Technology), Wuhan, Hubei 430070, PR China
Abstract:TiO2 films were fabricated by direct current reactive magnetron sputtering. The effect of the sputtering power on the film structures, morphologies, and properties was investigated in detail. It is found that the concentration of oxygen impurities increased with increasing sputtering power accompanied by the bandgap (Eg) narrowing and broadening of photoluminescence (PL) peaks. The oxygen impurities were found to mainly play the role of recombination centers, leading to the decrease of photocatalytic activity. Furthermore, the photoconductivity to dark conductivity ratio could be used to evaluate and even predict photocatalytic activity to some extent.
Keywords:Photocatalysis   Photoconductivity   Magnetron sputtering   Titatium dioxide   Thin films
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