| 硫醇转化催化剂及硫醇氧化反应机理研究进展 |
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| 引用本文： | 张玉芬,申宝剑. 硫醇转化催化剂及硫醇氧化反应机理研究进展[J]. 工业催化, 2009, 17(10): 7-11. DOI: 10.3969/j.issn.1008-1143.2009.10.002 |
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| 作者姓名： | 张玉芬 申宝剑 |
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| 作者单位： | 中国石油大学(北京),北京,102249;中国石油大学(北京),北京,102249 |
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| 摘 要： | 综述了国内外硫醇转化催化剂及硫醇氧化反应机理的研究概况。介绍了酞菁钴类硫醇转化催化剂、固体碱硫醇转化催化剂以及硫醇的碱催化氧化反应机理和氧化还原催化氧化反应机理。指出以新型硫醇转化催化剂取代目前工业上的酞菁钴类催化剂势在必行。
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| 关 键 词： | 催化化学 硫醇转化催化剂 硫醇脱除 氧化反应 机理 |
Latest studies on mercaptan conversion catalysts and mechanisms for mercaptan oxidation |
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| ZHANG Yufen,SHEN Baojian. Latest studies on mercaptan conversion catalysts and mechanisms for mercaptan oxidation[J]. Industrial Catalysis, 2009, 17(10): 7-11. DOI: 10.3969/j.issn.1008-1143.2009.10.002 |
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| Authors: | ZHANG Yufen SHEN Baojian |
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| Affiliation: | China University of Petroleum（Beijing）,Beijing 102249,China |
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| Abstract: | Abstract： Latest researches in mercaptan conversion catalysts and mechanisms for mercaptan oxidation were reviewed, including cobalt phthalocyanine and solid base catalysts, as well as base-catalyzed mer- captan oxidation reaction mechanism and redox catalytic mercaptan oxidation mechanism. It was pointed out that substitution of cobalt phthalocyanine by novel mercaptan conversion catalysts would be the trends in this aspect. |
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| Keywords: | catalytic chemistry mercaptan conversion catalyst mercaptan sweetening oxidation reaction mechanism |
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