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双子表面活性剂有序聚集体的形成
引用本文:李轶,展思辉. 双子表面活性剂有序聚集体的形成[J]. 日用化学工业, 2008, 38(6)
作者姓名:李轶  展思辉
作者单位:天津大学,理学院,化学系,天津,300072;南开大学,环境科学与工程学院,天津,300071
基金项目:山东大学胶体和界面化学教育部重点实验室开放课题 , 天津大学青年教师B类培养基金  
摘    要:综述了gemini(双子)表面活性剂的分子结构以及溶液的浓度、温度、pH值和反离子等因素对gemini表面活性剂聚集行为的影响。通过调整以上因素可以有目的地调控gemini表面活性剂有序聚集体的形成。这些有序聚集体不仅在生产和生活中有重要应用,而且与生命活动中的一系列现象密切相关,受到各个领域科学家的广泛重视。尽管gemini表面活性剂所形成的各种聚集体已经得到了广泛证实,但对形成的机理和实际应用的研究仍比较薄弱。

关 键 词:双子表面活性剂  聚集体  胶束  囊泡

Formation of self-assembled aggregates of gemini surfactant
LI Yi,ZHAN Si-hui. Formation of self-assembled aggregates of gemini surfactant[J]. China Surfactant Detergent & Cosmetics, 2008, 38(6)
Authors:LI Yi  ZHAN Si-hui
Abstract:Effects of molecular structure as well as factors such as concentration of surfactant solution,temperature,pH value and counter ion on the self-assembling behavior of gemini surfactants were reviewed.Through changes of the above-mentioned factors,the formation of self-assembled aggregates can be adjusted and controlled purposely.Such self-assembled aggregates not only have important applications in industrial production as well as in personal life,but also correlated with a series of life activity phenomena.Nevertheless various self-assembled aggregates of gemini surfactant have been well proven by experiments,the study on mechanism of their formation and their practical applications are not yet well developed.
Keywords:gemini surfactant  self-assembly  micelle  vesicle
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