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CdS/Cu纳米光催化剂降解废水中的HMX和RDX试验研究(英)
作者姓名:Hamid Reza Pouretedal  Mohammad Hossien Keshavarz  Mohammad Hasan Yosefi  Arash Shokrollahi  Abbas Zali
作者单位:Faculty of Science,Malek-ashtsr University of Technology
摘    要:The wastewater with HMX and RDX was treated by photodegradation process in the presence of cadmium sulfide doped with copper as photocatalyst under UV and Vis irradiations.The influence on the degration of Cu% as dopant in CdS/Cu nanoparticles,pH of solution,dosage of photocatalyst and concentration of explosives were studied.The XRD patterns and UV-Vis spectra were used to characterize the nanoparticle.Results show that the degradation efficiency for HMX and RDX wastewater reaches 85%-88% in the presence of Cd0.95Cu0.05S under 180 min UV irradiation.The dosage of 160.0 mg·L-1 of photocatalyst and the pH of 7 are the optimum.A gradual decrease in degradation at the first two cycles is seen.

关 键 词:硫化镉光电管  光降解  光催化剂  RDX
收稿时间:2008/3/18 0:00:00

Photocatalytic Degradation of HMX and RDX Wastewater with CdS/Cu Nanophotocatalyst
Hamid Reza Pouretedal,Mohammad Hossien Keshavarz,Mohammad Hasan Yosefi,Arash Shokrollahi,Abbas Zali.Photocatalytic Degradation of HMX and RDX Wastewater with CdS/Cu Nanophotocatalyst[J].Chinese Journal of Energetic Materials,2008,16(6):745-752.
Authors:Hamid Reza Pouretedal
Affiliation:Faculty of Science, Malek-ashtsr University of Technology, Shahin-shahr, Iran
Abstract:The wastewater with HMX and RDX was treated by photodegradation process in the presence of cadmium sulfide doped with copper as photocatalyst under UV and Vis irradiations. The influence on the degration of Cu% as dopant in CdS/Cu nanoparticles, pH of solution, dosage of photocatalyst and concentration of explosives were studied. The XRD patterns and UV-Vis spectra were used to characterize the nanoparticle. Results show that the degradation efficiency for HMX and RDX wastewater reaches 85%-88% in the presence of Cd0.95Cu0.05S under 180 min UV irradiation. The dosage of 160.0 mg·L-1 of photocatalyst and the pH of 7 are the optimum. A gradual decrease in degradation at the first two cycles is seen.
Keywords:cadmium sulfide  nanoparticle  photodegradation  photocatalyst  RDX  HMX
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