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Ice-templated assembly strategy to construct oriented porous Ti3SiC2 ceramics for thermal management and electromagnetic interference shielding in harsh thermal environments
Affiliation:1. College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211100, China;2. Key Laboratory of Material Preparation and Protection for Harsh Environment (Nanjing University of Aeronautics and Astronautics), Ministry of Industry and Information Technology, Nanjing 211100, China;1. National Key Laboratory of Science and Technology for National Defense on Advanced Composites in Special Environments, Harbin Institute of Technology, 150001 Harbin, Heilongjiang Province, China;2. Postdoctoral Research Center for Material Science and Engineering, Harbin Institute of Technology, 150001 Harbin, Heilongjiang Province, China;1. Department of Materials Science and Engineering, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan;2. Department of Materials Science and Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 891-0395, Japan;3. Next Generation Zirconia Social Cooperation Program, Institute of Engineering Innovation, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan
Abstract:Given the electromagnetic interference (EMI) and heat aggregation issue faced by electronic components, an urgent need exists to integrate EMI shielding and thermal conductivity in one material. Herein, a novel lightweight porous Ti3SiC2 ceramic with ordered structural arrangement was fabricated by using budget-friendly raw materials through ice template design and in-situ reaction synthesis. Leveraging the excellent conductivity and thermal conductivity of Ti3SiC2, a dual-functional advanced material with efficient EMI shielding and thermal management capabilities was obtained. At room temperature, porous Ti3SiC2 ceramics can achieve a shielding effectiveness of 35.44 dB and a thermal conductivity of 12.17 W/mK, with performance that can be tuned by porosity. In further, the porous Ti3SiC2 ceramic can work stably in thermal environments from room temperature to 700 °C or in corrosive environments rich in acid, alkali, and salts due to its excellent high temperature oxidation resistance and corrosion resistance. In view of the dual-functional characteristics and the stability of operation in harsh thermal environments, ordered porous Ti3SiC2 ceramics are promising for modern maritime and aerospace applications.
Keywords:Ordered porous structure  Electromagnetic interference shielding  Thermal conductivity  Harsh thermal environment
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