Direct determination of transference numbers of LiClO4 solutions in propylene carbonate and acetonitrile |
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| Affiliation: | 1. Dipartimento di Chimica, Università di Roma “La Sapienza”, P.le A. Moro 5, 00185 Rome, Italy;2. Dipartimento di Scienze del Farmaco, Università degli Studi “G.D’Annunzio”, Via dei Vestini, 31, 66013 Chieti, Italy;3. MaxPower, Inc., 220 Stahl Road, Harleysville, PA 19438, USA;1. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 122 Luoshi Road, Wuhan 430070, PR China;2. Department of Chemistry, School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, 122 Luoshi Road, Wuhan 430070, China;3. Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory, Xianhu Hydrogen Valley, Foshan 528200, China;4. State Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan 430074, China;1. The Key Laboratory of Fuel Cell Technology of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, China;2. Electrochemical Energy Engineering Research Center of Guangdong Province, South China University of Technology, Guangzhou 510640, China;3. Department of Mechanical Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong, China;1. Materials Science & Engineering Program and Texas Materials Institute, The University of Texas at Austin, Austin, TX 78712, United States;2. Key Laboratory of Super Engineering Plastic of Ministry of Education, Jilin University, Qianjin Street 2699, Changchun 130012, PR China;3. McKetta Department of Chemical Engineering, The University of Texas at Austin, Austin, TX 78712, United States |
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| Abstract: | Transference number measurements were determined by a direct method for LiClO4 solutions in propylene carbonate and acetonitrile at 25 °C. A comparison is reported between theoretical calculations of transference numbers using a model based on the Lee–Wheaton theory with values of conductometric parameters, and thermodynamic ion pairing constants determined from previously reported conductivity data. |
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