| Eu3+掺杂的硼酸锶系列荧光体的合成及其发光性能 |
| |
| 引用本文： | 王海英,王如骥,张玥,李亚栋.Eu3+掺杂的硼酸锶系列荧光体的合成及其发光性能[J].无机材料学报,2004,19(6):1367-1372. |
| |
| 作者姓名： | 王海英 王如骥 张玥 李亚栋 |
| |
| 作者单位： | 清华大学化学系,北京,100084 |
| |
| 基金项目： | 国家自然科学基金(20151001) |
| |
| 摘 要： | 采用溶胶-凝胶法和高温固相反应法合成了Eu^3 掺杂的SrB4O7、SrB2O4、Sr2B2O5、Sr3B2O6荧光体．荧光光谱测试结果表明在不同基质中Eu^3 的荧光发射是有区别的，Sr2B2O5：Eu^3 、Sr3B2O7：Eu^3 发射峰在610nm左右的红光区，SrB2O4：Eu^3 的发射峰在593nm的橙色区，而SrB4O7：Eu^3 则表现出了Eu^2 离子的特征峰，产生这种区别主要是由Eu^3 所处的配位环境不同造成的．荧光体SrB4O7：Eu^3 、SrB2O4：Eu^3 、Sr2B2O5：Eu^3 、Sr3B2O6：Eu^3 的最佳掺杂浓度为2％左右．
|
| 关 键 词： | 硼酸锶 溶胶-凝胶 荧光特性 高温固相 |
| 文章编号： | 1000-324X(2004)06-1367-06 |
| 收稿时间： | 2003-10-27 |
| 修稿时间： | 2003-12-22 |
Synthesis and Luminescent Properties of Eu3+ Doped Strontium Borate Phosphors |
| |
| WANG Hai-Ying,WANG Ru-Ji,ZHANG Yue,LI Ya-Dong.Synthesis and Luminescent Properties of Eu3+ Doped Strontium Borate Phosphors[J].Journal of Inorganic Materials,2004,19(6):1367-1372. |
| |
| Authors: | WANG Hai-Ying WANG Ru-Ji ZHANG Yue LI Ya-Dong |
| |
| Affiliation: | ChemistryDepartmentofTsinghuaUniversity;Beijin100084;China |
| |
| Abstract: | Eu3+ doped borate phosphors (SrB4O7, SrB2O4, Sr2B2O5, Sr3B2O6) were prepared by solid state reaction and sol-gel technique, respectively. The luminescent results showed that the four kinds of phosphors have different luminescent properties. The Sr2B2O5:Eu3+, Sr3B2O7:Eu3+ phosphors have the red emission at 610nm, the SrB2O4:Eu3+ phosphor has the orange emission at 593nm, however the SrB4O7:Eu3+ phosphor displays the emission peaks of Eu2+ ion, all that result from the different Eu-O coordination environment. The optimal doping concentration of phosphors is 2%. |
| |
| Keywords: | strontium borate luminescent properties solid state reaction sol-gel technique |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《无机材料学报》浏览原始摘要信息 |
|
点击此处可从《无机材料学报》下载全文 |
|
